5A Molecular Sieve
Summary
5A molecular sieve, also called Calcium A molecular
sieve, non-toxic, odorless, nonflammable, non-explosive, insoluble in water and
organic solvents, but soluble in strong acid and strong base. Its pore diameter
is 5×10-10m, can adsorb any molecules which pore diameter is smaller than
5×10-10m. In addition to the effect of 3A, 4A molecular sieves, it also can
adsorb C3-C4 n-alkanes, ethylene chloride, bromoethane, butanol, etc. Yuanying
5A molecular sieve can be applied to pressure swing adsorption separation,
heterogeneous hydrocarbon separation and coadsorption of water and carbon
dioxide. 5A molecular sieve has ion exchange capacity and catalytic activity,
also has a great affinity to water, under high temperature still has good
adsorption ability, it has good catalysis to some organic gas phase reaction.
Yuanying 5A molecular sieve has excellent adsorption performance, high
mechanical strength, large specific surface areas and big pore volume.
Production
Let sodium aluminate, sodium silicate and sodium
hydroxide hybrid reaction according to certain molar ratio (normally
Al2O3:SiO2:Na2O:H2O=1:2:3:185), keeping temperature>40℃, with violent stirring, heating up reaction
gel to102℃±2℃, remain this temperature till static
crystallization, then filtration washing, adding calcium chloride for ion
exchange (exchange 70%), then filtration washing, drying, adding adhesives
kneading, molding, finally burning activating get 5A molecular sieve.
Application
1. The depth desiccation and purification of gases and
liquids, purification of nitrogen, hydrogen, cleaning hydrogen sintering
furnace
2. Through a selective adsorption process, isolated
n-alkane from branched-chain hydrocarbon and cyclic hydrocarbon, currently in
industry used for large-scale pressure alkane separation process
3. Desiccation, desulfurization, removal of carbon
dioxide for petroleum, petroleum gas and natural gas
4. Nitrogen oxygen separation, nitrogen hydrogen
separation, making oxygen, nitrogen and hydrogen
5. Petroleum dewaxing, can be used as a adsorbent in
dewaxing technology based on vapour as desorbent.
5A molecular sieve
regeneration
1. Moisture removal: According to pressure, temperature
and water of regenerate gas. Normally 200~350℃ dry gas under 0.3~0.5kg/cm through molecular sieve bed layer
3-4 hours, exit temperature 110~180℃, then cooling.
2. Removing organic matter: Used vapour instead of
organic matter, then repeat step 1.
Storage
On room temperature, relative humidity not more than
90%; not lay bare in the air; keep away from water, acid and soda